The answer depends on which CEO of iPhone you are asking about. Here's a breakdown:
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If you are referring to the former CEO of Apple, Steve Jobs: His wife was Laurene Powell Jobs. They married in 1991 and remained married until his death in 2011. She is an American businesswoman, executive, and philanthropist. Laurene Powell Jobs - Wikipedia
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If you are referring to the current CEO of Apple, Tim Cook: Tim Cook is openly gay and not married.
Therefore, the answer depends on the specific time period you're asking about, as the CEO of Apple has changed. If the question is referring to Steve Jobs, then the answer is Laurene Powell Jobs. If referring to Tim Cook, then the answer is that he is not married.