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How Do You Make Fully Synthetic Oil?

Published in Lubricant Manufacturing 5 mins read

Fully synthetic oil is a highly engineered lubricant manufactured by chemically modifying petroleum components or synthesizing base oils from other raw materials, resulting in a more uniform and higher-performing product than conventional mineral oils. While diverse raw materials can be used, the base material for synthetic lubricants is still overwhelmingly crude oil that is distilled and then modified physically and chemically. This meticulous process ensures superior lubrication properties and extended performance.

The Core Process of Synthesizing Fully Synthetic Oil

Unlike conventional oils that are simply refined from crude oil, fully synthetic oils involve a more complex and precise manufacturing process. This process focuses on creating uniform molecular structures, which provide superior performance characteristics.

Starting Materials: Beyond Raw Crude

The perception that synthetic oil is made from entirely different "raw materials" is partially true, but the reality is more nuanced. As referenced, synthetic lubricants can indeed be manufactured using chemically modified petroleum components rather than just whole crude oil. This means taking specific, processed fractions of crude oil and subjecting them to further rigorous chemical transformations.

Additionally, synthetic oils can also be synthesized from other raw materials. This includes sources like natural gas (via Gas-to-Liquid processes), coal, or even renewable biomass. However, it's crucial to understand that the base material, however, is still overwhelmingly crude oil that is distilled and then modified physically and chemically. This emphasizes the predominant role of petroleum, albeit in a highly processed and reformed state.

Molecular Engineering: The Key to Superiority

The primary distinction of synthetic oil lies in its molecular uniformity. Through advanced chemical processes, the irregular molecules found in crude oil are broken down and then rebuilt into highly consistent and uniform molecular structures. This precision engineering leads to several performance advantages. The general steps involved in creating synthetic base oils include:

  1. Distillation: Crude oil is initially distilled to separate various fractions, similar to conventional oil production. However, for synthetic oils, specific, cleaner fractions are targeted.
  2. Cracking and Hydroprocessing: Selected fractions undergo intensive processes like hydrocracking. Here, large, complex hydrocarbon molecules are broken down into smaller, more stable ones under high pressure and hydrogen, removing impurities like sulfur and nitrogen.
  3. Synthesis (Polymerization/Esterification): These smaller, pure molecules are then chemically reacted (synthesized) to create new, uniform molecules. Examples include:
    • Polyalphaolefins (PAOs): Synthesized from ethylene gas (a byproduct of petroleum refining or natural gas) into long, stable polymer chains with predictable characteristics.
    • Esters: Created by reacting specific alcohols with carboxylic acids, which can be derived from various sources, including non-petroleum ones.
  4. Purification: The synthesized base oil undergoes rigorous purification steps to remove any remaining impurities, waxes, and other undesirable compounds, resulting in an exceptionally pure base fluid.

Common Base Oil Groups Used in Synthetics

The American Petroleum Institute (API) categorizes base oils into five groups based on their composition and manufacturing process. Fully synthetic oils primarily utilize Group III, Group IV, and Group V base oils due to their superior purity and molecular uniformity.

API Group Base Oil Type Source Material Description
Group III Hydrocracked Mineral Oil (VHVI) Heavily hydrocracked crude oil (petroleum-based) Highly refined and extensively processed mineral oil. Its molecular structure is significantly altered to resemble synthetics, offering improved performance over conventional mineral oils. Often marketed as "synthetic" in many regions, representing "chemically modified petroleum components."
Group IV Polyalphaolefins (PAO) Ethylene gas (derived from petroleum or natural gas) True synthetic hydrocarbons created by polymerizing alpha-olefins. Known for excellent thermal stability, oxidation resistance, and superior low-temperature flow characteristics. These are a cornerstone of high-performance synthetic lubricants.
Group V Other Synthetics (Esters, PAGs, etc.) Various, including organic acids/alcohols (non-petroleum or petroleum-derived) Encompasses all other base oils not covered in Groups I-IV. Common examples include Esters (known for excellent solvency, detergency, and high-temperature performance) and Polyalkylene Glycols (PAGs). Often blended with PAOs for enhanced properties and specific applications, representing "other raw materials."

The Role of Additives in Fully Synthetic Oil

While the base oil provides the fundamental lubrication properties, it's the carefully selected blend of additives that truly defines the final performance of a fully synthetic oil. These additives typically constitute 15-30% of the final product and are critical for meeting modern engine demands.

Key additive categories include:

  • Viscosity Index Improvers (VIIs): Help maintain oil viscosity across a wide temperature range, ensuring consistent lubrication from cold starts to hot operating conditions.
  • Antioxidants: Prevent oil degradation due to oxidation, especially at high temperatures, extending oil life.
  • Detergents and Dispersants: Keep engine parts clean by preventing sludge and varnish formation, carrying contaminants in suspension until they are filtered out.
  • Anti-wear Agents: Form a protective film on metal surfaces, particularly at points of high pressure, to reduce friction and wear.
  • Corrosion Inhibitors: Protect metallic engine components from rust and corrosion caused by moisture and acids.
  • Pour Point Depressants: Ensure the oil flows freely at very low temperatures, allowing for rapid lubrication upon startup in cold climates.

Why Molecular Uniformity Matters

The meticulous process of creating uniform molecules in synthetic oil translates to tangible benefits for engine performance and longevity. This precise molecular structure minimizes internal friction, enhances stability, and improves the oil's interaction with engine components.

Benefits of molecular uniformity include:

  • Enhanced Thermal Stability: Synthetic oil resists breakdown at high temperatures more effectively, maintaining its protective qualities under extreme engine conditions.
  • Improved Cold Flow Properties: The uniform molecules flow better in cold weather, allowing for quicker lubrication during startup and reducing wear on engine components.
  • Reduced Evaporation: Less volatility means less oil consumption and fewer harmful emissions, as fewer oil molecules vaporize at high temperatures.
  • Superior Shear Stability: Synthetic oil maintains its viscosity under extreme stress and high shear forces, protecting critical engine parts from metal-on-metal contact.
  • Cleaner Engine: By resisting sludge and deposit formation, synthetic oils help keep engine components cleaner, promoting optimal engine efficiency and longevity.