Density is a crucial property used to identify substances because each pure substance has a unique density at a given temperature and pressure. This means that by measuring the density of an unknown substance and comparing it to known densities, we can identify the substance.
Understanding Density
Density is defined as the mass of a substance per unit volume. The formula is:
Density (ρ) = Mass (m) / Volume (V)
This simple relationship allows us to calculate density if we know the mass and volume of a sample. Different substances have different densities because their atoms or molecules are packed differently, and their individual masses differ.
Using Density for Identification
The process of identifying a substance using density involves these steps:
- Measure the mass: Use a balance to precisely measure the mass of the unknown sample.
- Measure the volume: Determine the volume of the sample using appropriate methods, such as water displacement for irregularly shaped objects or direct measurement for regularly shaped objects.
- Calculate the density: Use the formula (ρ = m/V) to calculate the density of the unknown substance.
- Compare to known values: Consult a reference table or database of known densities for various substances. Compare the calculated density to these values. A close match strongly suggests the identity of the unknown substance.
Examples
- Gold: Gold has a very high density (approximately 19.3 g/cm³). This high density helps distinguish it from other metals.
- Water: Water has a density of approximately 1 g/cm³ at 4°C. This is a well-known benchmark density.
- Ethanol: Ethanol (alcohol) has a lower density than water, around 0.79 g/cm³. This difference in density is exploited in separating them via distillation.
Why Density, Not Just Mass or Volume?
While both mass and volume are important properties, they alone are not sufficient for identification. The mass and volume of a substance can change depending on the amount of the sample, but the density remains constant for a given pure substance at a specific temperature and pressure. This constant property makes density a powerful tool for identification. Multiple sources confirm this. For example, Socratic and Chemistry LibreTexts both highlight the unique and identifying nature of a substance's density.